Patent · US Expired

Aramid fibrils

US7629047B2 · kind B2 · utility

0Cited by
6References
16Claims
0Family size

Assignee

Inventors

Key dates

Filing dateNov 30, 2004
Grant dateDec 8, 2009
Priority date
Expiry dateDec 11, 2025

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY10T428/2969
  • WIPO fieldTextile and paper machines
  • WIPO sectorMechanical engineering

Abstract

Aramid fibrils having in the wet phase a Canadian Standard Freeness (CSF) value less than 100 ml, after drying a specific surface area (SSA) less than 7 m2/g, and a weight weighted length for particles having a length >250 μm (WL 0.25) less than 1.2 mm, are described. A method of preparing the fibrils includes the steps (a) polymerizing an aromatic diamine and an aromatic dicarboxylic acid halide to an aramid polymer, in a mixture of N-methylpyrrolidone or dimethylacetamide and calcium chloride or lithium chloride to obtain a dope wherein the polymer is dissolved in the mixture and the polymer concentration is 2 to 6 wt. %, (b) converting the dope to fibrils by using a jet spin nozzle under a gas stream, and (c) coagulating the fibrils using a coagulation jet.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.