Patent · US Active

Uranium dioxide electrolysis

US7638026B1 · kind B1 · utility

16Cited by
9References
9Claims
0Family size

Assignee

Inventors

Key dates

Filing dateAug 24, 2005
Grant dateDec 29, 2009
Priority date
Expiry dateMar 28, 2028

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC25C3/34
  • WIPO fieldSurface technology, coating
  • WIPO sectorChemistry

Abstract

This is a single stage process for treating spent nuclear fuel from light water reactors. The spent nuclear fuel, uranium oxide, UO2, is added to a solution of UCl4 dissolved in molten LiCl. A carbon anode and a metallic cathode is positioned in the molten salt bath. A power source is connected to the electrodes and a voltage greater than or equal to 1.3 volts is applied to the bath. At the anode, the carbon is oxidized to form carbon dioxide and uranium chloride. At the cathode, uranium is electroplated. The uranium chloride at the cathode reacts with more uranium oxide to continue the reaction. The process may also be used with other transuranic oxides and rare earth metal oxides.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.