Method for removing manganese from nickel laterite waste liquors
US7641801B2 · kind B2 · utility
Assignee
Inventors
Key dates
| Filing date | Feb 28, 2007 |
| Grant date | Jan 5, 2010 |
| Priority date | — |
| Expiry date | Jul 6, 2028 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY10S210/912
- WIPO fieldEnvironmental technology
- WIPO sectorChemistry
Abstract
A method and system of removing or decreasing waste liquor manganese concentration to less than about 1 mg/L total manganese without the precipitation of significant amounts of magnesium. The method and system include steps for treating the waste liquor using three separate circuits in which in the first circuit, manganese is reduced, for example, from about 2 g/L to <500 mg/L using pH adjustment with a suitable neutralizing agent; and in the second circuit, the final target manganese level is achieved by oxidative precipitation using a suitable oxidizing agent. Part of the precipitated manganese product, e.g., MnO2, is recycled to the oxidative precipitation circuit as seed and the balance proceeds to a third circuit wherein the precipitated manganese product is re-dissolved, and then recycled to the first neutralization circuit. In the first neutralization circuit and the second oxidative precipitation circuit, the process conditions are selected to minimize the precipitation of magnesium, e.g., Mg(OH)2.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.