Precipitated iron catalyst for hydrogenation of carbon monoxide
US7879756B2 · kind B2 · utility
Assignee
Inventors
Key dates
| Filing date | Aug 11, 2008 |
| Grant date | Feb 1, 2011 |
| Priority date | — |
| Expiry date | Nov 29, 2028 |
Classification
- Technology area (CPC B)Performing Operations; Transporting
- CPC primaryB01J2235/15
- WIPO fieldChemical engineering
- WIPO sectorChemistry
Abstract
A method of producing an iron catalyst for catalyzing the hydrogenation of carbon monoxide is disclosed. The method comprises using a reduced amount of acid for iron dissolution compared to certain previous methods. The resulting acidic iron mixture is heated without boiling to obtain a nitrate solution having a Fe2+:Fe3+ ratio in the range of about 0.01%:99.99% to about 100%:0% (wt:wt). Iron phases are precipitated at a lower temperature compared to certain previous methods. The recovered catalyst precursor is dried and sized to form particles having a size distribution between 10 microns and 100 microns. In embodiments, the Fe2+:Fe3+ ratio in the nitric acid solution may be in the range of from about 3%:97% to about 30%:70% (wt:wt) and the calcined catalyst may comprise a maghemite:hematite ratio of about 1%:99% to about 70%:30%.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.