Process for preparing long-chain polymethylene halide telomers
US7893186B2 · kind B2 · utility
Assignee
Inventors
Key dates
| Filing date | Dec 27, 2007 |
| Grant date | Feb 22, 2011 |
| Priority date | — |
| Expiry date | Jan 28, 2028 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY10T428/3154
- WIPO fieldMacromolecular chemistry, polymers
- WIPO sectorChemistry
Abstract
A process comprises combining in a batchwise, semi-continuous, or continuous manner, or a combination thereof, in the presence of at least one free radical initiator, and at a temperature sufficient to cause the initiator to fragment to form free radicals, (a) at least one telogen selected from (1) fluoroalkyl halides that comprise at least one halomethylene moiety (—CHX—) and, optionally, at least one non-fluorine heteroatom, and (2) perfluoroalkyl halides that comprise at least one halofluoromethylene moiety (—CFX—) and at least one non-halogen heteroatom, the halides being selected from iodides and bromides; and (b) ethylene; the telogen and the ethylene being combined in total amounts such that the number of moles of ethylene per mole of telogen is at least about 4.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.