Zeolite-containing hydrocarbon-converting catalyst, the preparation process thereof, and a process for converting hydrocarbon oils with the catalyst

US7923399B2 · kind B2 · utility

Assignees

• CHINA PETROLEUM & CHEMICAL CORPORATION · CN
• RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC · CN

Inventors

• Jun Long · Beijing, CN
• Zhijian Da · Beijing, CN
• Huiping Tian · Beijing, CN
• Zhenyu Chen · Beijing, CN
• Weilin Zhang · Nanhu, CN
• Xingtian Shu · Beijing, CN
• Jiushun Zhang · Beijing, CN
• Yuxia Zhu · Beijing, CN
• Yujian Liu · Beijing, CN

Key dates

• Filing date: Mar 31, 2005
• Grant date: Apr 12, 2011
• Expiry date: Jul 25, 2027

Classification

• Technology area (CPC C): Chemistry; Metallurgy
• CPC primary: C10G2400/20
• WIPO field: Chemical engineering
• WIPO sector: Chemistry

Abstract

A catalyst for converting hydrocarbons includes, based on the weight of the catalyst, 1-60% by weight of a zeolite, 0.1-10% by weight of an assistant catalytic component, 5-98% by weight of a thermotolerant inorganic oxide, and 0-70% by weight of a clay in terms of the oxide. The zeolite is a MFI-structured zeolite-containing phosphor and transition metal(s) or a mixture of the zeolite and a macroporous zeolite, which comprises, based on the weight of the mixture, 75-100% by weight of said MFI-structured zeolite containing phosphor and transition metal(s) and 0-25% by weight of the macroporous zeolite. In terms of the mass of the oxide, the MFI-structured zeolite containing phosphor and transition metal(s) has the following anhydrous chemical formula:(0-0.3)Na2O.(0.3-5.5)Al2O3.(1.0-10)P2O5.(0.7-15)M1xOy.(0.01-5)M2mOn(0-10)RE2O3.(70-97)SiO2  Ior(0-0.3)Na2O.(0.3-5)Al2O3.(1.0-10)P2O5.(0.7-15)MpOq.(0-10)RE2O3.(70-98)SiO2  IIThe assistant catalytic component is one or more selected from the group consisting of the alkali earth metals, Group IVB metals, non-noble metals of Group VIII, and rare earth metals of the Periodic Table of the Elements. This catalyst has a higher ability to conve…