Addition of (a) blocking agent(s) in a ceramic membrane for clocking crystalline growth of grains during atmospheric sintering

US7955526B2 · kind B2 · utility

Assignee

• L'Air Liquide, Société Anonyme à Directoire et Conseil de Surveillance pour l'Étude et l'Exploitation des Procédés Georges Claude · FR

Inventors

• Pascal Del Gallo · Étampes, FR
• Thierry Chartier · Riom, FR
• Gregory Etchegoyen · Limoges, FR

Key dates

• Filing date: Nov 5, 2004
• Grant date: Jun 7, 2011
• Expiry date: Apr 16, 2027

Classification

• Technology area (CPC Y): Emerging Cross-Sectional Technologies
• CPC primary: Y02P20/52
• WIPO field: Chemical engineering
• WIPO sector: Chemistry

Abstract

A composite material (M) comprising: at least 75% by volume of a mixed electronic conductor compound oxygen anions O<2->(C1) selected from doped ceramic compounds which, at the temperature of use, are present in the form of a crystalline network having ion oxide lattice vacancies and, more particularly, in the form of a cubic phase, a fluorite phase, a perovskite phase, of the aurivillius variety, a Brown-Millerite phase or a pyrochlore phase; and 0.01%-25% by volume of a compound (C2) which is different from compound (C1), selected from oxide-type ceramic materials, non-oxide type ceramic materials, metals, metal alloys or mixtures of said different types of material; and 0%-2.5% by volume of a compound (C3) produced from at least one chemical reaction represented by the equation: xFC1+yFC2 - - - >zFC3, wherein FC1, FC2 and FC3 represent the raw formulae of compounds (C1), (C2) and (C3) and x, y and z represent rational numbers above or equal to 0. The invention also relates to a method for the preparation and use thereof as mixed conductor material for a membrane catalytic reactor used to synthesize synthetic gas by catalytic oxidation of methane or natural gas and/or as mixed co…