Transition metal complex, catalyst composition including the same and olefin polymer using catalyst composition
US8039671B2 · kind B2 · utility
Assignee
Inventors
Key dates
| Filing date | Mar 7, 2011 |
| Grant date | Oct 18, 2011 |
| Priority date | — |
| Expiry date | Mar 7, 2031 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY10S526/943
- WIPO fieldOrganic fine chemistry
- WIPO sectorChemistry
Abstract
Provided are a novel transition metal complex where a monocyclopentadienyl ligand to which an amido group is introduced is coordinated, a catalyst composition including the same, and an olefin polymer using the catalyst composition. The transition metal complex has a pentagon ring structure having an amido group connected by a phenylene bridge in which a stable bond is formed in the vicinity of a metal site, and thus, a sterically hindered monomer can easily approach the transition metal complex. By using a catalyst composition including the transition metal complex, a linear low density polyolefin copolymer having a high molecular weight and a very low density polyolefin copolymer having a density of 0.910 g/cc or less can be produced in a polymerization of monomers having large steric hindrance. Further, the reactivity for the olefin monomer having large steric hindrance is excellent.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.