Catalyst for gas phase hydrogenation of carboxylic acids having a support modified with a reducible metal oxide
US8080694B2 · kind B2 · utility
15Cited by
109References
20Claims
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Key dates
| Filing date | Jun 30, 2011 |
| Grant date | Dec 20, 2011 |
| Priority date | — |
| Expiry date | Jun 30, 2031 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY02P20/52
- WIPO fieldChemical engineering
- WIPO sectorChemistry
Abstract
A process for selective formation of ethanol from acetic acid includes contacting a feed stream containing acetic acid and hydrogen at an elevated temperature with catalyst comprising platinum and tin on a high surface area silica promoted with calcium metasilicate. Selectivities to ethanol of over 85% are achieved at 280° C. with catalyst life in the hundreds of hours.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.