Patent · US Active

Reactive distillation with olefin recycle

US8148589B2 · kind B2 · utility

8Cited by
4References
20Claims
0Family size

Assignee

Inventors

Key dates

Filing dateJun 29, 2006
Grant dateApr 3, 2012
Priority date
Expiry dateJun 12, 2028

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY02P20/582
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

Process for producing alkene(s) from a feedstock containing at least one monohydric aliphatic paraffinic primary (or secondary) alcohol(s), consisting of ethanol or propanol(s) or a mixture thereof. The process includes the steps of converting the monohydric aliphatic paraffinic primary (or secondary) alcohol(s) into the corresponding same carbon number alkene(s) in a reactive distillation column at elevated pressure and temperature so that the heads stream extracted from the top of the reactive distillation column comprises essentially the alkene(s), cooling the heads stream from the first step to a temperature sufficient to condense at least part of the alkene(s) with the highest boiling point, recycling at least part of the condensed alkene(s) from the second step back into the reactive distillation column, as a reflux return, and simultaneously recovering the remaining alkene(s).

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.