Process for the selective oxidation of methane

US8217206B2 · kind B2 · utility

Assignee

• Total Petrochemicals Research Feluy · BE

Inventors

• Hendrik DE WINNE · Neustadt, DE
• Pierre Jacobs · Gooik, BE
• Bert Sels · Balen, BE
• Walter Vermeiren · Houthalen-Helchteren, BE

Key dates

• Filing date: Jul 4, 2008
• Grant date: Jul 10, 2012
• Expiry date: Jul 4, 2028

Classification

• Technology area (CPC B): Performing Operations; Transporting
• CPC primary: B01J2219/2487
• WIPO field: Chemical engineering
• WIPO sector: Chemistry

Abstract

The present invention is a process for converting methane to methanol, comprising: Advantageously the internal surface is made of quartz or coated with quartzAdvantageously the internal surface, made of silica (advantageously quartz) or coated with silica (advantageously quartz), is treated with HF before the conversion of methane to methanol.Advantageously the reaction is carried out in the absence in said reaction zone of any added material which measurably affects the rate of the reaction or the yield of the product.Advantageously the reactor is operated under a pressure from 1 to 7.5 MPa.Advantageously the reactor is operated at a temperature from 300° C. to 600° C.Advantageously the reactor is operated at a residence time from 0.1 to 100 s.Advantageously the reactor is operated at a methane to oxygen molar ratio from 1 to 50.The present invention also relates to a reactor having an internal surface made of silica (advantageously quartz) or coated with silica (advantageously quartz).