Patent · US Active

Tunable catalyst gas phase hydrogenation of carboxylic acids

US8309772B2 · kind B2 · utility

60Cited by
113References
108Claims
0Family size

Assignee

Inventors

Key dates

Filing dateOct 26, 2009
Grant dateNov 13, 2012
Priority date
Expiry dateJul 16, 2031

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY02P20/52
  • WIPO fieldChemical engineering
  • WIPO sectorChemistry

Abstract

A process for selective formation of ethanol from acetic acid includes contacting a feed stream containing acetic acid and hydrogen at an elevated temperature with catalyst comprising platinum and tin on a high surface area silica promoted with calcium metasilicate. Selectivities to ethanol of over 85% are achieved at 280° C. with catalyst life in the hundreds of hours.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.