Patent · US Active

Monomodal coupled diene elastomer having a silanol functional group in the middle of the chain, its process of preparation and rubber composition comprising it

US8344063B2 · kind B2 · utility

42Cited by
1References
22Claims
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Key dates

Filing dateApr 15, 2008
Grant dateJan 1, 2013
Priority date
Expiry dateSep 20, 2029

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC08K5/17
  • WIPO fieldMacromolecular chemistry, polymers
  • WIPO sectorChemistry

Abstract

The present invention relates to a monomodal coupled diene elastomer having a silanol functional group in the middle of the chain, to its process of preparation and to a rubber composition which can be used in particular in the manufacture of tire covers, having improved hysteresis and physical properties in the vulcanized state and an improved processing in the raw state, comprising a monomodal diene polymer having a silanol functional group in the middle of the chain and a reinforcing inorganic filler. The process for obtaining this elastomer having a silanol functional group in the middle of the chain comprises a reaction of the diene monomer(s) and of the polymerization initiator in the presence of a chelating polar agent, a reaction of the living diene polymer with a coupling agent and then, after hydrolysis, a recovery of the coupled diene polymer having a functional group in the middle of the chain. A rubber composition according to the invention comprises a reinforcing inorganic filler and this monomodal elastomer having a silanol functional group in the middle of the chain.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.