Surface stabilized electrodes for lithium batteries
US8383077B2 · kind B2 · utility
Assignee
Inventors
Key dates
| Filing date | Feb 14, 2012 |
| Grant date | Feb 26, 2013 |
| Priority date | — |
| Expiry date | Feb 14, 2032 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY02T10/70
- WIPO fieldElectrical machinery, apparatus, energy
- WIPO sectorElectrical engineering
Abstract
A method of stabilizing a metal oxide or lithium-metal-oxide electrode comprises contacting a surface of the electrode, prior to cell assembly, with an aqueous or a non-aqueous acid solution having a pH greater than 4 but less than 7 and containing a stabilizing salt, for a time and at a temperature sufficient to etch the surface of the electrode and introduce stabilizing anions and cations from the salt into said surface. The structure of the bulk of the electrode remains unchanged during the acid treatment. The stabilizing salt comprises fluoride and at least one cationic material selected from the group consisting of ammonium, phosphorus, titanium, silicon, zirconium, aluminum, and boron.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.