Method for preparing a dialkyl carbonate of dianhydrohexitol
US8399601B2 · kind B2 · utility
Assignee
Inventors
Key dates
| Filing date | Sep 30, 2010 |
| Grant date | Mar 19, 2013 |
| Priority date | — |
| Expiry date | Sep 30, 2030 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY02P20/582
- WIPO fieldOrganic fine chemistry
- WIPO sectorChemistry
Abstract
A method for preparing dialkyl carbonates of dianhydrohexitol, includes the following steps: (a) preparing an initial reaction mixture containing at least one dianhydrohexitol, at least two mole equivalents of a dialkyl carbonate of formula and a transesterification catalyst; (b) heating the reaction mixture to a temperature greater than or equal to the boiling temperature of the formed alcohol, or of the azeotrope thereof, in a reaction chamber preferably provided with a rectification column including a sufficient number of theoretical distillation plates to separate the resulting alcohol from the reaction mixture. Certain dialkyl carbonates of dianhydrohexitols produced by the method and the use thereof for synthesizing synthetic polymers are also described.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.