Cyclic catalytic upgrading of chemical species using metal oxide materials
US8435920B2 · kind B2 · utility
Assignee
Inventors
Key dates
| Filing date | Oct 11, 2010 |
| Grant date | May 7, 2013 |
| Priority date | — |
| Expiry date | Oct 11, 2030 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY02P30/40
- WIPO fieldChemical engineering
- WIPO sectorChemistry
Abstract
Processes are disclosure which comprise alternately contacting an oxygen-carrying catalyst with a reducing substance, or a lower partial pressure of an oxidizing gas, and then with the oxidizing gas or a higher partial pressure of the oxidizing gas, whereby the catalyst is alternately reduced and then regenerated to an oxygenated state. In certain embodiments, the oxygen-carrying catalyst comprises at least one metal oxide-containing material containing a composition having the following formulas: (a) CexByB′zB″Oδ, wherein B=Ba, Sr, Ca, or Zr; B′=Mn, Co, and/or Fe; B″=Cu; 0.01<x<0.99; 0<y<0.6; 0<z<0.5; (b) Ce1-x-yNixByO2-*, wherein B=Zr, Ba, Ca, La, or K; 0.02<x<0.1; 0<y<0.1; and 0.02<*<0.15; and 1<δ<2.2 and (c) coal ash either as a catalyst material itself or as a support for said unary or binary metal oxides.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.