Process for preparing carboxylic esters by reactive distillation

US8455676B2 · kind B2 · utility

Assignee

• BASF SE

Inventors

• Helmut Kronemayer · Heidelberg, DE
• Ellen Dahlhoff · Schifferstadt, DE
• Andreas Lanver · Mannheim, DE

Key dates

• Filing date: Apr 18, 2011
• Grant date: Jun 4, 2013
• Expiry date: Jun 21, 2031

Classification

• Technology area (CPC Y): Emerging Cross-Sectional Technologies
• CPC primary: Y02P20/10
• WIPO field: Chemical engineering
• WIPO sector: Chemistry

Abstract

In a process for preparing carboxylic esters by transesterification, a first feed stream comprising a first carboxylic ester, e.g. methyl formate, is introduced laterally into a reaction column at least one first feed point located between top and bottom of the reaction column and a second feed stream comprising a first alcohol, e.g. ethanol, is introduced laterally into the reaction column at a second feed point located above the first feed point and are reacted in a reaction zone of the reaction column to form a second carboxylic ester and a second alcohol. The first alcohol has a higher molecular weight than the second alcohol. A product fraction comprising the second carboxylic ester and unreacted first carboxylic ester is taken off at an offtake point located above the second feed point. At the bottom of the reaction column, a bottom fraction comprising the second alcohol and unreacted first alcohol is taken off. The product fraction is separated by distillation at a pressure which is different from the pressure in the reaction column into second carboxylic ester and a fraction comprising unreacted first carboxylic ester and the fraction comprising unreacted first carboxylic e…