Patent · US Active

Heterocyclic amine catalyst compositions for the alkoxylation of alcohols to glycol ethers

US8541629B2 · kind B2 · utility

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10Claims
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Key dates

Filing dateApr 17, 2009
Grant dateSep 24, 2013
Priority date
Expiry dateFeb 26, 2030

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC07C43/13
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

Glycol ethers are made by a process in which an alcohol, an alkylene oxide and a catalytic amount of an aromatic, heterocyclic amine catalyst are contacted under reactive conditions. Representative catalysts include substituted and unsubstituted pyridines and imidazoles. The process uses known oxides and alcohols, and produces more mono- and di-adduct products than does a corresponding process using a caustic catalyst. Moreover, the process can be conducted at a lower reaction temperature than a corresponding process using a caustic catalyst without sacrificing oxide conversion rates yet producing fewer carbonyl impurities.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.