Nanocomposite comprising exfoliated nanoclay-styrenic concentrate and methods of preparation
US8557908B2 · kind B2 · utility
Assignee
Inventor
Key dates
| Filing date | Mar 9, 2011 |
| Grant date | Oct 15, 2013 |
| Priority date | — |
| Expiry date | Feb 15, 2032 |
Classification
- Technology area (CPC C)Chemistry; Metallurgy
- CPC primaryC08L21/00
- WIPO fieldMacromolecular chemistry, polymers
- WIPO sectorChemistry
Abstract
A composition is disclosed comprising a styrenic first polymer, nanoclay, and an emulsifier compound, which can be blended with an additional polymer. A nanocomposite exhibits improved heat resistant properties and stiffness. In one embodiment, the additional polymer is poly(phenylene ether). An article and a method for the preparation a nanocomposite are also disclosed. In one embodiment, the process of obtaining a nanocomposite comprises emulsion polymerizing styrenic monomers in the presence of an aqueous dispersion of nanoclay and emulsifier compound, wherein an aqueous mixed dispersion comprising styrenic polymer and nanoclay is formed; coagulating the aqueous mixed dispersion with a coagulating agent to form a coagulated mixed dispersion comprising nanoclay and styrenic polymer; solidifying the coagulated mixed dispersion to form a polymeric clay concentrate comprising the nanoclay and the styrenic polymer as a carrier resin; and mixing the polymeric nanoclay concentrate, directly or indirectly with an additional polymer to form a nanocomposite.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.