Process for the preparation of hydrocarbons from synthesis gas
US8598238B2 · kind B2 · utility
Assignee
Inventors
Key dates
| Filing date | Jun 3, 2010 |
| Grant date | Dec 3, 2013 |
| Priority date | — |
| Expiry date | Aug 4, 2030 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY02P30/20
- WIPO fieldBasic materials chemistry
- WIPO sectorChemistry
Abstract
A process for the preparation of hydrocarbon products comprising the steps of (a) providing a synthesis gas comprising hydrogen, carbon monoxide and carbon dioxide; (b) reacting the synthesis gas to an oxygenate mixture comprising methanol and dimethyl ether in presence of one or more catalysts which together catalyse a reaction of hydrogen and carbon monoxide to oxygenates at a pressure of at least 4 MPa; (c) withdrawing from step (b) the oxygenate mixture comprising amounts of methanol, dimethyl ether, carbon dioxide and water together with unreacted synthesis gas and introducing the entire amount of the oxygenate mixture without further treatment into a catalytic oxygenate conversion step (d); (d) reacting the oxygenate mixture in presence of a catalyst being active in the conversion of oxygenates to higher hydrocarbons; (e) withdrawing an effluent from step (d) and separating the effluent into a tail gas, a liquid hydrocarbon phase containing the higher hydrocarbons produced in step. (d) and a liquid aqueous phase, wherein the pressure employed in steps (c) to (e) is substantially the same as employed in step (b).
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.