Patent · US Active

Solid-stage polymerization system for a liquid crystalline polymer

US8618239B2 · kind B2 · utility

6Cited by
42References
18Claims
0Family size

Assignee

Inventors

Key dates

Filing dateSep 26, 2012
Grant dateDec 31, 2013
Priority date
Expiry dateSep 26, 2032

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC08G69/44
  • WIPO fieldMacromolecular chemistry, polymers
  • WIPO sectorChemistry

Abstract

A multi-stage process for forming a liquid crystalline polymer is provided. More particularly, the process includes acetylating one or more precursor monomers and melt-polymerizing the acetylated monomers to form a prepolymer in the form of a solid particulate material. Thereafter, the prepolymer is solid-state polymerized in a fluidized bed reactor that contains a porous surface (e.g., bed, plate, grate, etc.) on which the prepolymer is supported. While supported by this porous surface, the prepolymer can become “fluidized” with a heated stream of a gas (e.g., nitrogen). In this manner, a sufficient degree of turbulence is created to distribute heat evenly around the prepolymer and cause it to rapidly reach the target reaction temperature.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.