Vulcanizable nanoparticles having a core with a high glass transition temperature
US8697775B2 · kind B2 · utility
Assignee
Inventors
Key dates
| Filing date | Dec 20, 2006 |
| Grant date | Apr 15, 2014 |
| Priority date | — |
| Expiry date | Dec 31, 2027 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY10T428/2982
- WIPO fieldMacromolecular chemistry, polymers
- WIPO sectorChemistry
Abstract
Provided is a polymer nanoparticle comprising a core and a vulcanizable shell, wherein the core has a glass transition temperature (Tg) of at least about 150° C. Also provided is a method of preparing polymer nanoparticles with a core and a vulcanizable shell, comprising (a) in a liquid hydrocarbon medium, polymerizing conjugated diene monomers to produce a poly(conjugated diene) block and (b) copolymerizing the poly(conjugated diene) block with a mixture of mono-vinyl aromatic monomers and multiple-vinyl aromatic monomers to produce an aromatic block, wherein the core has a Tg of at least about 150° C. Also provided is a composition comprising (a) a rubber matrix; and (b) a polymer nanoparticle including a core and a vulcanizable shell; wherein the Tg of the core is at least about 150° C.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.