Process to prepare a hydrogen rich gas mixture
US8703094B2 · kind B2 · utility
Assignee
Inventors
Key dates
| Filing date | Jun 28, 2010 |
| Grant date | Apr 22, 2014 |
| Priority date | — |
| Expiry date | Sep 30, 2030 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY02E20/18
- WIPO fieldBasic materials chemistry
- WIPO sectorChemistry
Abstract
The invention is directed to a process to prepare a hydrogen rich gas mixture from a solid sulphur- and halogen-containing carbonaceous feedstock. The process involves the following steps. Step (a): gasification of the solid carbonaceous feedstock with an oxygen-containing gas to obtain a gas mixture comprising halogen compounds, sulphur compounds, hydrogen and at least 50 vol. % carbon monoxide, on a dry basis. Step (b): contacting the gas mixture with a quench gas or quench liquid to reduce the temperature of the gas mixture to below 900° C. Step (c) contacting the gas mixture with water having a temperature of between 150 and 250° C. to obtain a gas mixture comprising between 50 and 1000 ppm halogen and having a steam to carbon monoxide molar ratio of between 0.2:1 and 0.9:1. Step (d): subjecting the gas mixture obtained in step (c) to a water gas shift reaction wherein part or all of the carbon monoxide is converted with the steam to hydrogen and carbon dioxide in the presence of a catalyst as present in one fixed bed reactor or in a series of more than one fixed bed reactors and wherein the temperature of the gas mixture as it enters the reactor or reactors is between 190 and …
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.