Process for manufacturing acrolein from glycerol
US8829246B2 · kind B2 · utility
Assignee
Inventor
Key dates
| Filing date | Sep 11, 2008 |
| Grant date | Sep 9, 2014 |
| Priority date | — |
| Expiry date | Jul 17, 2029 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY02P20/52
- WIPO fieldOrganic fine chemistry
- WIPO sectorChemistry
Abstract
The subject of the present invention is a process for preparing acrolein by dehydration of glycerol in the presence of a catalyst system based on iron phosphorous oxide containing, in addition, one or more elements chosen from alkali metals, alkaline-earth metals, AI, Si, B, Co, Cr, Ni, V, Zn, Zr, Sn, Sb, Ag, Cu, Nb, Mo, Y, Mn, Pt, Rh and the rare earths La, Ce, Sm. The process is preferably carried out in the gas phase in the presence of oxygen starting from aqueous solutions of glycerol. The process according to the invention makes it possible of obtain high acrolein selectivities.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.