Production of alpha, omega-diols

US8846985B2 · kind B2 · utility

Assignee

• E.I. DU PONT DE NEMOURS AND COMPANY · US

Inventors

• Alan Martin Allgeier · Wilmington, US
• Wathudura Indika Namal De Silva · Rahway, US
• Carl Andrew Menning · Newark, US
• Joachim C. Ritter · Wilmington, US
• Sourav Kumar Sengupta · Wilmington, US

Key dates

• Filing date: Apr 25, 2013
• Grant date: Sep 30, 2014
• Expiry date: Apr 25, 2033

Classification

• Technology area (CPC C): Chemistry; Metallurgy
• CPC primary: C07C209/16
• WIPO field: Organic fine chemistry
• WIPO sector: Chemistry

Abstract

Disclosed herein are processes for preparing an α,ω-Cn-diol, wherein n is 5 or greater, from a feedstock comprising a Cn oxygenate. In one embodiment, the process comprises contacting the feedstock with hydrogen gas in the presence of a catalyst comprising a first metal component comprising Ni, Ir, Pt, Rh, Ru, Pd, Fe, Ag, or Au; a heteropoly acid component comprising H3[P(W3O10)4], H4[Si(W3O10)4], H4[P(Mo3O10)4], H4[Si(Mo3O10)4], Cs2.5H0.5[P(W3O10)4]Cs2.5H0.5[Si(W3O10)4], or mixtures thereof; optionally a second metal component comprising Cr, a Cr oxide, Ni, a Ni oxide, Fe, a Fe oxide, Co, a Co oxide, Mn, a Mn oxide, Mo, a Mo oxide, W, a W oxide, Re, a Re oxide, Zn, a Zn oxide, SiO2, or Al2O3; optionally at least one promoter comprising Na, K, Mg, Rb, Cs, Ca, Sr, Ba, Ce, or mixtures thereof; and optionally a support. In one embodiment, the optional support is present in the catalyst and comprises WO3, SiO2, Al2O3, carbon, TiO2, ZrO2, SiO2—Al2O3, montmorillonite, SiO2—TiO2, tungstated ZrO2, zeolites, V2O5, MoO3, or mixtures thereof. The Cn oxygenate may be obtained from a biorenewable resource.