Patent · US Active

Energy efficient synthesis of aliphatic aldehydes from alkenes and carbon dioxide

US8884070B2 · kind B2 · utility

9Cited by
1References
18Claims
0Family size

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Inventors

Key dates

Filing dateJun 16, 2011
Grant dateNov 11, 2014
Priority date
Expiry dateJun 16, 2031

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY02P20/00
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

Provided is a process for producing an aldehyde from an alkylene. The process includes (a) photocatalytically dehydrogenating at least one alkane to obtain a mixture comprising at least one olefin and hydrogen, (b) adding carbon dioxide and hydrogen to the mixture, and (c) hydroformylating the olefin to at least one aldehyde. The process also includes converting carbon dioxide and hydrogen into water and carbon monoxide prior to the hydroformylating. In addition, the conversion of carbon dioxide and hydrogen into water and carbon monoxide is performed by a reverse water gas shift reaction.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.