Methods and materials for the thermochemical production of hydrogen from water
US8940269B2 · kind B2 · utility
Assignee
Inventors
Key dates
| Filing date | Apr 2, 2013 |
| Grant date | Jan 27, 2015 |
| Priority date | — |
| Expiry date | Jul 31, 2033 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY02E60/36
- WIPO fieldMaterials, metallurgy
- WIPO sectorChemistry
Abstract
The present invention is directed to a method of thermochemical forming H2, O2, or a combination thereof from water, said method comprising the steps of contacting a composition comprising a spinel-type transition metal oxide of formula M3O4 with an alkali metal carbonate bicarbonate, or mixture thereof in the presence of H2O to form H2, CO2, and an alkali metal ion-transition metal oxide; hydrolytically extracting at least a portion of alkali metal ions from the alkali metal ion-transition metal oxide by the reaction with CO2 and liquid H2O; and thermochemically reducing the resulting oxidized-transition metal oxide. The thermochemical reduction of CO2 based on analogous methods is also disclosed.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.