Process for the preparation of oxovinylionol and its O-protected derivatives
US9061982B2 · kind B2 · utility
Assignee
Inventors
Key dates
| Filing date | Nov 9, 2012 |
| Grant date | Jun 23, 2015 |
| Priority date | — |
| Expiry date | Apr 25, 2033 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY02P20/55
- WIPO fieldOrganic fine chemistry
- WIPO sectorChemistry
Abstract
The present invention relates to the preparation of oxovinylionol and its O-protected derivatives of the formula Iin which R is hydrogen or an OH protecting group, for example a group Si(Ra)3, by reacting a compound of the general formula IIin which R has the meanings given above for formula I, i.e. β-vinyl ionol (formula II, R=hydrogen) or an O-protected derivative thereof (formula II, R═OH protecting group) with an oxidant in the presence of at least one transition metal, where the oxidant comprises at least one oxygen-containing compound which is selected from among hydrogen peroxide and organic hydroperoxides.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.