Patent · US Active

Method for preparing polymethylene polyphenyl polycarbamate

US9062161B2 · kind B2 · utility

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1References
17Claims
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Key dates

Filing dateNov 8, 2011
Grant dateJun 23, 2015
Priority date
Expiry dateNov 8, 2031

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY02P20/582
  • WIPO fieldMacromolecular chemistry, polymers
  • WIPO sectorChemistry

Abstract

A method for preparing polymethylene polyphenyl polycarbamate is provided. The method includes dissolving phenylcarbamate in a water-immiscible organic solvent to form a solution A, formulating an aqueous acid catalyst solution to form a solution B, forming a reaction system comprising an organic phase and an aqueous phase by firstly adding a methylating reagent to the solution B and then mixing the solution A and the solution B, wherein the organic phase comprises phenylcarbamate and the aqueous phase comprises the acid catalyst and the methylating reagent. The method further includes reacting the reaction system under stirring at a reaction temperature of 30° C. to 200° C. and a reaction pressure of 0.05 MPa to 5 MPa to produce a polymethylene polyphenyl polycarbamate product mixture dissolved in the organic phase, and separating the polymethylene polyphenyl polycarbamate product mixture by allowing the organic phase and the aqueous phase to stand still and stratify.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.