Patent · US Active

Process for the preparation of (meth)acrylic esters and derivatives

US9145371B2 · kind B2 · utility

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Key dates

Filing dateJun 11, 2014
Grant dateSep 29, 2015
Priority date
Expiry dateJun 11, 2034

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC07D233/32
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

Transesterification processes for producing a compound of formula (I)wherein R1 is H or a methyl group, A and B are each, independently, a linear or branched C2-C5 alkylene group, comprising reacting: an acrylate or methacrylate of formula (II)wherein R1 is H or a methyl group and R2 is a C1-C4 alkyl group, with a compound of formula (III)wherein the reaction is performed: (i) in the presence of calcium oxide and calcium hydroxide, and (ii) wherein the molar ratio of the compounds of formula (II) to formula (III) is less than 4:1 or 3:1 respectively.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.