Patent · US Active

Iron-comprising heterogeneous catalyst and process for preparing olefins by reaction of carbon monoxide with hydrogen

US9156026B2 · kind B2 · utility

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7Claims
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Key dates

Filing dateMar 1, 2013
Grant dateOct 13, 2015
Priority date
Expiry dateApr 10, 2034

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC10G2400/20
  • WIPO fieldChemical engineering
  • WIPO sectorChemistry

Abstract

A process for preparing olefins by reaction of carbon monoxide with hydrogen in the presence of a an iron-comprising heterogeneous catalyst produced by the following steps: thermal decomposition of gaseous iron pentacarbonyl to give carbonyl iron powder having spherical primary particles; treatment of carbonyl iron powder with hydrogen, resulting in the metallic spherical primary particles at least partially forming agglomerates; contacting the agglomerates with iron pentacarbonyl; and thermal decomposition of the iron pentacarbonyl to give at least predominantly pore-free and void-free secondary particles.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.