Iron-comprising heterogeneous catalyst and process for preparing olefins by reaction of carbon monoxide with hydrogen
US9156026B2 · kind B2 · utility
Assignee
Inventors
Key dates
| Filing date | Mar 1, 2013 |
| Grant date | Oct 13, 2015 |
| Priority date | — |
| Expiry date | Apr 10, 2034 |
Classification
- Technology area (CPC C)Chemistry; Metallurgy
- CPC primaryC10G2400/20
- WIPO fieldChemical engineering
- WIPO sectorChemistry
Abstract
A process for preparing olefins by reaction of carbon monoxide with hydrogen in the presence of a an iron-comprising heterogeneous catalyst produced by the following steps: thermal decomposition of gaseous iron pentacarbonyl to give carbonyl iron powder having spherical primary particles; treatment of carbonyl iron powder with hydrogen, resulting in the metallic spherical primary particles at least partially forming agglomerates; contacting the agglomerates with iron pentacarbonyl; and thermal decomposition of the iron pentacarbonyl to give at least predominantly pore-free and void-free secondary particles.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.