Method for producing phosphorus-containing flame retardants

US9238777B2 · kind B2 · utility

Assignee

• METADYNEA AUSTRIA GmbH · AT

Inventors

• Thomas Zich · Linz, AT
• Fritz Johann Freidl · Bezirk Krems an der Donau (Stadt), AT
• Bernadette Mehofer · Bezirk Krems an der Donau (Stadt), AT
• Manfred Döring · Bad Mergentheim, DE
• Michael Ciesielski · Orchard Park, US
• Bettina Burk · Darmstadt, DE

Key dates

• Filing date: Feb 27, 2015
• Grant date: Jan 19, 2016
• Expiry date: Feb 27, 2035

Classification

• Technology area (CPC C): Chemistry; Metallurgy
• CPC primary: C07F9/657154
• WIPO field: Organic fine chemistry
• WIPO sector: Chemistry

Abstract

A method for producing compounds of formula (I) in which the radical R1 is selected from —NH2, —NH2-zAz, and monovalent alkyl and aryl radicals, the radicals A are selected in each case independently of one another from the phosphoryl radicals DOPO-, DPhPO- and DPhOPO-, and the indices x, y and z, in each case independently of one another, stand for 0 or 1, wherein at least one of the indices is ≠0, by reacting, in a first step, melamine or, when R1 is an alkyl or aryl radical, the corresponding alkyl or aryl guanamine, with one or more of the corresponding phosphinyl chlorides DOP-CI, DPhP-Cl and DPhOP-CI, in order to bond one or more phosphinyl radicals to the amino groups(s) of the melamine or guanamine, and in a second step oxidizing the phosphinyl radical(s) by reaction with an oxidizing agent to give the corresponding phosphoryl radical(s).