Process for methanol coupled catalytic cracking reaction of naphtha using a modified ZSM-5 molecular sieve catalyst

US9284235B2 · kind B2 · utility

Assignee

• DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES · CN

Inventors

• Zhongmin Liu · 东风镇, CN
• Yingxu Wei · Dalian, CN
• Yue Qi · Dalian, CN
• Mao Ye · Dalian, CN
• Mingzhi Li · Dalian, CN
• Bing Li · Towaco, US
• Xiangao Wang · Dalian, CN
• Changqing He · Dalian, CN
• Xinde Sun · Dalian, CN

Key dates

• Filing date: Jun 24, 2011
• Grant date: Mar 15, 2016
• Expiry date: May 5, 2032

Classification

• Technology area (CPC Y): Emerging Cross-Sectional Technologies
• CPC primary: Y02P30/40
• WIPO field: Basic materials chemistry
• WIPO sector: Chemistry

Abstract

The present invention provides a process for methanol coupled catalytic cracking reaction of naphtha using a modified ZSM-5 molecular sieve catalyst, comprising performing a co-feeding reaction of methanol and naphtha on the modified ZSM-5 molecular sieve catalyst to produce low carbon olefins and/or aromatic hydrocarbons. In the process, the modified ZSM-5 molecular sieve catalyst comprises, in term of weight percent, 25-80 wt % of a ZSM-5 molecular sieve, 15-70 wt % of a binder, and 2.2-6.0 wt % of lanthanum and 1.0-2.8 wt % of phosphorus loaded on the ZSM-5 molecular sieve. The naphtha comprises 63.8-89.5 wt % of saturated chain alkanes and 5.6-29.8 wt % of cyclic alkanes. The naphtha and methanol concurrently pass through the catalyst bed, which are reacted during contacting with the catalyst under a reaction condition of a reaction temperature of 550-670° C., a mass ratio of methanol to naphtha of 0.05-0.8, and a total mass space velocity of naphtha and methanol of 1.0-5 h−1.