Production and use of zinc amides

US9334237B2 · kind B2 · utility

Assignee

• Ludwig-Maximilians-Universitat Munchen · DE

Inventors

• Paul Knochel · Marburg, DE
• Marc Mosrin · Monheim, DE

Key dates

• Filing date: Feb 11, 2010
• Grant date: May 10, 2016
• Expiry date: Feb 11, 2030

Classification

• Technology area (CPC C): Chemistry; Metallurgy
• CPC primary: C07F3/003
• WIPO field: Organic fine chemistry
• WIPO sector: Chemistry

Abstract

A reagent of the formulaR1R2N—ZnY LiY  (I)wherein R1 and R2 are independently, selected from H, aryl or heteroaryl, linear, branched or cyclic, substituted or unsubstituted alkyl, alkenyl, alkynyl, or silyl derivatives thereof; and R1 and R2 together form part of a cyclic or polymeric structure; R1 and/or R2 is not H; Y is F, Cl, Br, I, CN, SCN, NCO or HalOn, wherein n=3 or 4 and Hal is Cl, Br or I; NO3; BF4; PF6; H; a carboxylate of formula R5CO2; an alcoholate of formula OR5; a thiolate of formula SR5; R5P(O)O2; or SCOR5; or SCSR5; OnSR5; wherein n=2 or 3; or NOn, wherein n=2 or 3; and a derivative thereof; wherein R5 is an aryl or heteroaryl, linear, branched or cyclic, alkyl, alkenyl, alkynyl, or derivatives thereof, or H; or as adduct with a solvent; and preparation and use thereof.