Lithium sulfide-carbon complex, process for producing the complex, and lithium ion secondary battery utilizing the complex
US9337476B2 · kind B2 · utility
Assignee
Inventors
Key dates
| Filing date | Aug 24, 2009 |
| Grant date | May 10, 2016 |
| Priority date | — |
| Expiry date | Sep 22, 2030 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY02P70/50
- WIPO fieldElectrical machinery, apparatus, energy
- WIPO sectorElectrical engineering
Abstract
The present invention provides a process for producing a lithium sulfide-carbon composite, the process comprising placing a mixture of lithium sulfide and a carbon material having a specific surface area of 60 m2/g or more in an electrically-conductive mold in a non-oxidizing atmosphere, and applying a pulsed direct current to the mold while pressurizing the mixture in a non-oxidizing atmosphere, thereby subjecting the lithium sulfide and the carbon material to heating reaction; and a lithium sulfide-carbon composite obtained by this process, the composite having a carbon content of 15 to 70 weight %, and a tap density of 0.4 g/cm3 or more when the carbon content is 30 weight % or more, or a tap density of 0.5 g/cm3 or more when the carbon content is less than 30 weight %. The present invention can improve the electronic conductivity of lithium sulfide, which is expected to be put into practical use as a high-capacity positive electrode active material, so as to further enhance the performance of lithium sulfide as a positive electrode active material for lithium ion secondary batteries.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.