Lithium-ion battery anode including core-shell heterostructure of silicon coated vertically aligned carbon nanofibers
US9362549B2 · kind B2 · utility
Assignee
Inventors
Key dates
| Filing date | Jul 3, 2013 |
| Grant date | Jun 7, 2016 |
| Priority date | — |
| Expiry date | Feb 8, 2034 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY10T29/49115
- WIPO fieldElectrical machinery, apparatus, energy
- WIPO sectorElectrical engineering
Abstract
A novel hybrid lithium-ion anode material based on coaxially coated Si shells on carbon nanofibers (CNF). The unique cup-stacking graphitic microstructure makes the CNFs an effective Li+ intercalation medium. Highly reversible Li+ intercalation and extraction were observed at high power rates. More importantly, the highly conductive and mechanically stable CNF core optionally supports a coaxially coated amorphous Si shell which has much higher theoretical specific capacity by forming fully lithiated alloy. Addition of surface effect dominant sites in close proximity to the intercalation medium results in a hybrid device that includes advantages of both batteries and capacitors.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.