One-step intermolecular electrocyclic rearrangement process
US9371262B2 · kind B2 · utility
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Key dates
| Filing date | Oct 26, 2012 |
| Grant date | Jun 21, 2016 |
| Priority date | — |
| Expiry date | Dec 24, 2032 |
Classification
- Technology area (CPC C)Chemistry; Metallurgy
- CPC primaryC07C2602/20
- WIPO fieldOrganic fine chemistry
- WIPO sectorChemistry
Abstract
A direct acid catalyzed intermolecular electrocyclic rearrangement process for the preparation of linear and cyclic homoallylic ester and amides. A one step intermolecular electrocyclic rearrangement process includes the step of reacting a beta, gamma-unsaturated aldehyde or ketone, in which the beta, gamma-unsaturation is not part of an aromatic ring, with another aldehyde or a secondary aldimine in the presence of an acid.
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