Patent · US Active

One-step intermolecular electrocyclic rearrangement process

US9371262B2 · kind B2 · utility

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Key dates

Filing dateOct 26, 2012
Grant dateJun 21, 2016
Priority date
Expiry dateDec 24, 2032

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC07C2602/20
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

A direct acid catalyzed intermolecular electrocyclic rearrangement process for the preparation of linear and cyclic homoallylic ester and amides. A one step intermolecular electrocyclic rearrangement process includes the step of reacting a beta, gamma-unsaturated aldehyde or ketone, in which the beta, gamma-unsaturation is not part of an aromatic ring, with another aldehyde or a secondary aldimine in the presence of an acid.

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