Method for the preparation of Li1+αV3O8
US9373835B2 · kind B2 · utility
Assignees
Inventors
Key dates
| Filing date | Apr 5, 2013 |
| Grant date | Jun 21, 2016 |
| Priority date | — |
| Expiry date | May 23, 2034 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY02E60/10
- WIPO fieldElectrical machinery, apparatus, energy
- WIPO sectorElectrical engineering
Abstract
The invention relates to a lithium vanadium oxide which corresponds to the formula Li1+αV3O8 (0.1≦α≦0.25). It is composed of agglomerates of small needles having a length l from 400 to 1000 nm, a width w such that 10<l/w<100 and a thickness t such that 10<l/t<100. It is obtained by a process consisting in preparing a precursor gel by bringing α-V2O5 and a Li precursor into contact in amounts such that the ratio of the concentrations [V2O5]/[Li] is between 1.15 and 1.5 and in subjecting the gel to a heat treatment comprising a first stage at 80° C.-150° C. for 3 h to 15 days and a second stage between 250° C. and 350° C. for 4 min to 1 hour, under a nitrogen or argon atmosphere. It is useful as an active material of a positive electrode.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.