Hydrothermal process for the production of LiFePO4 powder
US9484574B2 · kind B2 · utility
Inventors
Key dates
| Filing date | Nov 10, 2009 |
| Grant date | Nov 1, 2016 |
| Priority date | — |
| Expiry date | Jun 16, 2032 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY02P70/50
- WIPO fieldElectrical machinery, apparatus, energy
- WIPO sectorElectrical engineering
Abstract
The present invention relates to a process for the production of LiFePO4 powder, comprising the steps: a) providing an aqueous solution of an organic surfactant; b) providing an aqueous solution of an iron (II) salt and mixing said aqueous iron (II) salt solution with an aqueous solution of a phosphate, to provide a mixed iron (II) salt/phosphate solution having a stoichiometric ratio of Fe2+:phosphate of about 1:1; c) adding the mixed iron (II) salt/phosphate solution to the surfactant solution under constant stirring; d) providing an aqueous solution comprising a lithium salt, adding said aqueous solution comprising a lithium salt to said mixed iron (II) salt/phosphate solution to provide a mixture having a stoichiometric ratio of Fe2+:phosphate:lithium salt of about 1:1:3 and stirring the resulting mixture; e) heating the resulting mixture at 80-200° C.; f) washing the resulting precipitate to remove excess surfactant, filtering and drying the precipitate; and g) heat treating the dried precipitate in an inert atmosphere by firing at 550-850° C. for at least 2 hours, wherein a co-solvent is added during or after any one of steps (a) to (d).
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.