Polymerization solution, conductive polymer film obtained from the polymerization solution, and solid electrolytic capacitor
US9558891B2 · kind B2 · utility
Assignee
Inventors
Key dates
| Filing date | Mar 1, 2012 |
| Grant date | Jan 31, 2017 |
| Priority date | — |
| Expiry date | Dec 9, 2033 |
Classification
- Technology area (CPC H)Electricity
- CPC primaryH01G9/15
- WIPO fieldElectrical machinery, apparatus, energy
- WIPO sectorElectrical engineering
Abstract
Disclosed is a polymerization solution for electrolytic polymerization containing borodisalicylic acid and/or a salt thereof as a supporting electrolyte, in which precipitation due to the hydrolysis of borodisalicylate ions is inhibited and which provides a conductive polymer exhibiting excellent heat resistance. The polymerization solution has: a solvent consisting of 100 to 80% by mass of water and 0 to 20% by mass of an organic solvent; at least one monomer having a π-conjugated double bond; at least one supporting electrolyte selected from the group consisting of borodisalicylic acid and borodisalicylic salts; and at least one stabilizing agent selected from the group consisting of nitrobenzene and nitrobenzene derivatives, and the content of the stabilizing agent content is more than ⅛ mol per 1 mol of the supporting electrolyte. A complex is formed by the stabilizing agent and borodisalicylic acid, and the formation of precipitation due to the hydrolysis of borodisalicylate ions is inhibited.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.