Tethered transition metals promoted photocatalytic system for efficient hydrogen evolutions
US9579639B2 · kind B2 · utility
Assignees
Inventors
Key dates
| Filing date | Sep 4, 2014 |
| Grant date | Feb 28, 2017 |
| Priority date | — |
| Expiry date | Sep 30, 2034 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY02E60/36
- WIPO fieldChemical engineering
- WIPO sectorChemistry
Abstract
The present invention is directed, at least in part, to a process for improving the efficiency of a photocatalyst (a semiconductor photocatalyst) by tethering (depositing) a metal (e.g., metal ions of a late transition metal, such as nickel) to the semiconductor (photocatalyst) surface through the use of an organic ligand. More specifically, 1,2-ethanedithiol (EDT) functions as an excellent molecular linker (organic ligand) to attach a transition metal complex (e.g., nickel (Ni2+ ions)) to the semiconductor surface, which can be in the form of a cadmium sulfide surface. The photocatalyst has particular utility in generating hydrogen from H2S.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.