Solvent-supported compaction of metal-organic frameworks
US9757710B1 · kind B1 · utility
Assignee
Inventors
Key dates
| Filing date | Aug 19, 2016 |
| Grant date | Sep 12, 2017 |
| Priority date | — |
| Expiry date | Aug 19, 2036 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY02E60/32
- WIPO fieldChemical engineering
- WIPO sectorChemistry
Abstract
Methods of forming a high surface area compacted MOF powder are disclosed, as well as MOF pellets formed thereby. The method may include synthesizing a metal organic framework (MOF) powder using a first solvent, exchanging the first solvent with a second solvent such that pores of the MOF powder are at least 10% filled with the second solvent, compacting the MOF powder having pores at least 10% filled with the second solvent into a pellet, and desolvating the compacted pellet to remove the second solvent. The pellet may maintain a specific surface area after compacting that is at least 80% its initial specific surface area. Compacting the MOF powder with a solvent at least partially filling its pores may prevent or reduce crushing of the MOF pore structure and maintain surface area, for example, for hydrogen or natural gas storage.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.