Chromium-free catalyst for gas-phase fluorination and application thereof
US9845274B2 · kind B2 · utility
Assignee
Inventors
Key dates
| Filing date | Aug 5, 2014 |
| Grant date | Dec 19, 2017 |
| Priority date | — |
| Expiry date | Aug 5, 2034 |
Classification
- Technology area (CPC C)Chemistry; Metallurgy
- CPC primaryC07C21/18
- WIPO fieldOrganic fine chemistry
- WIPO sectorChemistry
Abstract
Disclosed in the present invention is a chromium-free catalyst for gas-phase fluorination and an application thereof. The precursor of the related chromium-free catalyst for gas-phase fluorination consists of a compound containing iron element, a compound containing rare earth metal element and a compound containing element A, wherein element A is one selected from Ca, Al, Mg and Ti, the precursor is subjected to calcination and fluorination treatment to obtain the chromium-free catalyst for gas-phase fluorination. The precursor of the catalyst is calcined at 400-500° C. and fluorinated with hydrogen fluoride at 350-450° C. to obtain the chromium-free fluorinated catalyst. The catalyst has characteristics of being chromium-free and environment-friendly, good catalytic activity and long life etc. The catalyst can be used for preparing hydrofluoroolefins or hydrochlorofluoroolefins from halohydrocarbons.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.