Method of improving metal-impregnated catalyst performance
US9868117B2 · kind B2 · utility
Assignee
Inventors
Key dates
| Filing date | Mar 9, 2015 |
| Grant date | Jan 16, 2018 |
| Priority date | — |
| Expiry date | Mar 9, 2035 |
Classification
- Technology area (CPC C)Chemistry; Metallurgy
- CPC primaryC10G2400/30
- WIPO fieldChemical engineering
- WIPO sectorChemistry
Abstract
A method of reducing the amount of carbon monoxide present during the metal reduction step of start-up, thus, maintaining metal dispersion and improving the metal reduction and catalyst yields. Carbon monoxide formation is minimized during the start-up procedure and during the initial catalyst dryout phase in a hydrogen-containing atmosphere, gas is purged from the reactor system, either continuously at constant pressure or by a series of pressure/depressure cycles, to remove carbon monoxide. The purging is conducted at temperatures of about 30-500° C. and pressures of about −90-5,000 kPa(g) (−0.9-50 bar(g)). In this temperature range, carbon monoxide absorbed to the surface of the metal will desorb into the hydrogen-containing atmosphere and can be removed from the system along with carbon monoxide present in the atmosphere through the purging.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.