Method for preparing (meth)acrylates of biobased alcohols and polymers thereof
US9908837B2 · kind B2 · utility
Assignee
Inventors
Key dates
| Filing date | Mar 13, 2014 |
| Grant date | Mar 6, 2018 |
| Priority date | — |
| Expiry date | Apr 17, 2034 |
Classification
- Technology area (CPC C)Chemistry; Metallurgy
- CPC primaryC07C2531/10
- WIPO fieldOrganic fine chemistry
- WIPO sectorChemistry
Abstract
Polymers, particularly those used in pressure-sensitive adhesives, are prepared from a mixture of structural isomers of a secondary alkyl (meth)acrylate monomer. The mixture is made by dehydrating a biobased C2-C22 alcohol with a first acid catalyst using a continuous process to form a mixture of olefins, and reacting (meth)acrylic acid with at least some of the mixture of olefins in the presence of a second acid catalyst. The adhesives are characterized by exhibiting an overall balance of adhesive and cohesive characteristics, and containing biobased material.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.