Method for recycling pyrolysis tail gas through conversion into formic acid
US10760004B2 · kind B2 · utility
Assignees
Inventors
Key dates
| Filing date | Mar 26, 2018 |
| Grant date | Sep 1, 2020 |
| Priority date | — |
| Expiry date | Aug 1, 2038 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY02P20/54
- WIPO fieldBasic materials chemistry
- WIPO sectorChemistry
Abstract
This disclosure describes systems and methods for using pyrolysis tail gas as the source for additional hydrogen to be used in the pyrolysis reaction. Tail gas is separated from the pyrolysis products and a portion of the tail gas is converted into formic acid (HCOOH). The formic acid is then injected into the pyrolysis reactor where it becomes the donor of two monohydrogen atoms and is ultimately converted into CO2 under reaction conditions. In this fashion, a closed loop pyrolysis hydrogen donor system may be created utilizing a generally non-toxic intermediary derived from the pyrolysis reaction products. This disclosure also describes using a ruthenium catalyst supported on particles of activated carbon to improve the yield of pyrolysis reactions.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.