Patent · US Expired

Nucleotide analog composition and synthesis method

US5935946A · kind A · utility

84Cited by
3References
20Claims
0Family size

Assignee

Inventors

Key dates

Filing dateJul 25, 1997
Grant dateAug 10, 1999
Priority date
Expiry dateJul 25, 2017

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC07F9/65616
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

The invention provides a composition comprising bis(POC)PMPA and fumaric acid (1:1). The composition is useful as an intermediate for the preparation of antiviral compounds, or is useful for administration to patients for antiviral therapy or prophylaxis. The composition is particularly useful when administered orally. The invention also provides methods to make PMPA and intermediates in PMPA synthesis. Embodiments include lithium t-butoxide, 9-(2-hydroxypropyl) adenine and diethyl p-toluenesulfonylmethoxyphosphonate in an organic solvent such as DMF. The reaction results in diethyl PMPA preparations containing an improved by-product profile compared to diethyl PMPA made by prior methods.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.