Patent · US Expired

Method and chemical sensor for determining concentrations of hydrogen peroxide and its precursor in a liquid

US6042714A · kind A · utility

65Cited by
3References
26Claims
0Family size

Assignee

Inventors

Key dates

Filing dateDec 4, 1997
Grant dateMar 28, 2000
Priority date
Expiry dateDec 4, 2017

Classification

  • Technology area (CPC G)Physics
  • CPC primaryG01N31/228
  • WIPO fieldMeasurement
  • WIPO sectorInstruments

Abstract

A new method which employs a mixed-valence cluster of M.sub.y.sup.z+ [Fe(II)(CN).sub.6 ] coated on an electrode surface to determine hydrogen peroxide concentration electrochemically is developed. M of the mixed-valence compound can be Co, Ni, Cr, Sc, V, Cu, Mn, Ag, Eu, Cd, Zn, Ru or Rh; z is the valence state of M; and y=4/z. In addition, this invention also reveals a new approach to determine a concentration of a hydrogen peroxide precursor, wherein a catalyst is immobilized in the matrix or on the surface of the mixed-valence compound on the electrode. In a typical biochemical system, the catalyst can be a glucose oxidase and blood sugar is catalyzed to form hydrogen peroxide.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.