Patent · US Expired

Electroless copper employing hypophosphite as a reducing agent

US6046107A · kind A · utility

3Cited by
12References
7Claims
0Family size

Assignee

Inventors

Key dates

Filing dateDec 17, 1998
Grant dateApr 4, 2000
Priority date
Expiry dateDec 17, 2018

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC23C18/40
  • WIPO fieldSurface technology, coating
  • WIPO sectorChemistry

Abstract

Method and baths for electroless depositing Cu on a semiconductor chip using four preferred Cu electroless baths. All four preferred electroless baths use hypophosphite as a reducing agent. The 4 baths use the following mediators (1) Nickel sulfate, (2) Pd Sulfate (3) Co Sulfate (4) Fe Sulfite, and complexing agents (Na Citrite, Boric Acid, Ammonium Sulfite). The baths can operate at a pH between 8 and 10. The invention forms high purity Cu interconnects having adequate step coverage to form in a hole having an aspect ratio greater than 2.7 to 1.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.