Patent · US Expired

Low etch alkaline zincate composition and process for zincating aluminum

US6080447A · kind A · utility

11Cited by
15References
10Claims
0Family size

Assignee

Inventors

Key dates

Filing dateMay 14, 1998
Grant dateJun 27, 2000
Priority date
Expiry dateMay 14, 2018

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC23F1/20
  • WIPO fieldSurface technology, coating
  • WIPO sectorChemistry

Abstract

A method is provided for zincating aluminum substrates for metal plating thereon wherein the plated aluminum product has smoothness, dimensional integrity and increased production yield of the plated products. The substrates also have enhanced paramagnetic thermal stability of ENP coatings used on memory disk products. A zincate bath contains as additives Fe.sup.+3 and NaNO.sub.3, and a chelator to chelate the iron, with a preferred iron chelator being Rochelle Salt and with the amount of Fe.sup.+3 being controlled at a preferred concentration of 0.2 to 0.3 g/l. A preferred zincating method employs an etchant composition comprising HNO.sub.3, H.sub.2 S0.sub.4 and H.sub.3 PO.sub.4 to etch the aluminum substrate prior to zincating. Use of this etchant composition, either alone or with the zincate bath of the invention, is particularly effective for aluminum substrates which have been ground to a smoothness of less than 100 .ANG.. The etchant is non-aggressive and removes metal oxides formed by the grinding and annealing process to form the aluminum substrates used to fabricate the memory disks. The etchant also preserves the dimensional integrity of the substrate and prepares the sur…

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.